MAIN-GROUP ATRANES - CHEMICAL AND STRUCTURAL FEATURES

被引：374

作者：

VERKADE, JG

机构：

来源：

COORDINATION CHEMISTRY REVIEWS | 1994年 / 137卷

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0010-8545(94)03007-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Atranes are comprised of two bridgehead atoms bridged by three three-atom moieties. When the bridgehead atoms interact, a [3.3.3.0]tricyclic system is produced; when they do not, a [3.3.3]bicyclic structure is evident. Quasi-tricyclic structures are also known in which the bridgehead-bridgehead bond length lies between the sum of the van der Waals radii and a normal transannular bond. Because of this and additional factors, atranes give rise to interesting new and useful chemistry as well as novel molecular architectures. In this review the chemical reactivities and structural properties of main group atrane systems are surveyed.

引用

页码：233 / 295

页数：63

共 272 条

[41] The Gas-Phase Molecular Structure of 1-Fluorosilatrane from Electron Diffraction [J].