IDENTIFICATION OF BUTATRIENEDIONE, ITS RADICAL-ANION, AND ITS RADICAL CATION IN THE GAS-PHASE

被引：20

作者：

SULZLE, D ^{[1
]}

SCHWARZ, H ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期

关键词：

D O I：

10.1002/anie.199009081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Butatrienedione is also detectable mass spectroscopically: electron impact ionization of 1 affords, via elimination of CO2 and Me2CO, the radical anion OC4O•⊖, which can be converted by vertical charge reversal into the corresponding cation. In neutralization‐reionization experiments, starting from both species it was possible to obtain the neutral molecule. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：908 / 909

页数：2

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