SYNTHESIS AND CRYSTAL-STRUCTURE OF A DINUCLEAR COPPER(II) COMPLEX WITH A NOVEL TETRAPYRAZOLYL MACROCYCLE

被引：23

作者：

BOL, JE ^{[1
]}

DRIESSEN, WL ^{[1
]}

REEDIJK, J ^{[1
]}

机构：

[1] LEIDEN UNIV,LEIDEN INST CHEM,GORLAEUS LABS,2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 13期

关键词：

D O I：

10.1039/c39950001365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel 30-membered macrocycle containing four endocylic, neutral pyrazole groups, binds two Cu-II ions, where a flexible propylene spacer separates the Cu-II ions by 7.14 Angstrom; the crystals structure of the mixed-anion complex[CU2(L)Cl-2(EtOH)(2)](NO3)2 shows that each Cu-II ion is bound in a square-pyramidal N(4)X chromophore.

引用

页码：1365 / 1366

页数：2

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