BETA-ACYLVINYL ANION EQUIVALENTS - PREPARATION OF 1-LITHIO-3-(TERT-BUTYLDIMETHYLSILOXY)-1,3-CYCLOHEXADIENE AND ITS REACTION WITH ELECTROPHILES

被引：35

作者：

PIERS, E

MORTON, HE

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 19期

关键词：

D O I：

10.1021/jo01333a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-Lithio-3-(tert-butyldimethylsiloxy)-1, 3-cyclohexadiene (21), conveniently prepared by transmetalation of the trialkylstannyl derivatives 18 and 20 with methyllithium and n-butyllithium, respectively, reacts smoothly with various electrophilic reagents to form, in excellent yields, the corresponding 1-substituted 3-(tert-butyldimethylsiloxy)-1, 3-cyclohexadienes (23). © 1979, American Chemical Society. All rights reserved.

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页码：3437 / 3439

页数：3

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