A NEW SYSTEM FOR ALKANE OXIDATION - MODIFICATION OF GIF-TYPE REACTIONS USING O-2/H-2 WITH A PD CATALYST

被引：10

作者：

KIM, SB ^{[1
]}

JUN, KW ^{[1
]}

KIM, SB ^{[1
]}

LEE, KW ^{[1
]}

机构：

[1] KOREA RES INST CHEM TECHNOL,DIV CATALYSIS RES,TAEJON 305600,SOUTH KOREA

来源：

CHEMISTRY LETTERS | 1995年 / 07期

关键词：

D O I：

10.1246/cl.1995.535

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have investigated the modification of Gif-type reactions using hydrogen peroxide formed in situ by the palladium catalyzed combining of oxygen and hydrogen. The oxidation of cyclohexane in the solvent mixture, acetone-acetic acid, gives cyclohexanol and cyclohexanone with rather high yields, but any solvent containing pyridine is not suitable for the modified system.

引用

页码：535 / 536

页数：2

共 12 条

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