THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .19. APPLICATION OF TERT-BUTYL HYDROPEROXIDE AND DIOXYGEN USING SOLUBLE FE(III) AND CU(II) CHELATES

被引：27

作者：

BARTON, DHR ^{[1
]}

BEVIERE, SD ^{[1
]}

HILL, DR ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLL STN,TX 77843

来源：

TETRAHEDRON | 1994年 / 50卷 / 09期

关键词：

OXIDATION; SELECTIVE FUNCTIONALIZATION; IRON AND COPPER CATALYSTS;

D O I：

10.1016/S0040-4020(01)86982-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New methodology for the selective transformation of saturated hydrocarbons into ketones/alcohols and alkenes is described. A crucial aspect of this new process is that no reaction solvent is required since the Fe(III) and Cu(II) complexes used are completely soluble in the hydrocarbon substrates. Thus, the large quantity of pyridine, acetic acid or acetonitrile required in previous systems is no longer a prerequisite.

引用

页码：2665 / 2670

页数：6

共 21 条

[1] METAL DEPENDENCE IN GIF-TYPE REACTIONS - THE CU(II)-CATALYZED OLEFINATION OF SATURATED-HYDROCARBONS BY TERT-BUTYL HYDROPEROXIDE [J].