METAL DEPENDENCE IN GIF-TYPE REACTIONS - THE CU(II)-CATALYZED OLEFINATION OF SATURATED-HYDROCARBONS BY TERT-BUTYL HYDROPEROXIDE

被引：12

作者：

BARTON, DHR

BEVIERE, SD

CHAVASIRI, W

DOLLER, D

HU, B

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)61621-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cycloalkanes are transformed into the corresponding cycloalkenes by treatment with tert-butyl hydroperoxide (TBHP) in pyridine/acetic acid solution in the presence of Cu(OAC)2.H2O. When iron salts are used instead of copper salts, the major reaction product is the corresponding ketone. Differences between the iron-catalyzed and the copper-catalyzed reactions support a metal-dependent reaction pathway.

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页码：567 / 570

页数：4

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