SYNTHETIC METHODS .40. A SYNTHESIS OF (-) SUPINIDINE AND ITS REGIOISOMER BY INTRAMOLECULAR OXIME OLEFIN CYCLOADDITION

被引：28

作者：

HASSNER, A

SINGH, S

SHARMA, R

MAURYA, R

机构：

[1] Department of Chemistry, Bar-Ilan University, Ramat-Gan

来源：

TETRAHEDRON | 1993年 / 49卷 / 11期

关键词：

D O I：

10.1016/S0040-4020(01)80375-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthesis of (-) supinidine 1 and its regioisomer 2 from L-proline is described. The key step is a thermal intramolecular oxime-olefin cycloaddition; dimerization products resulting from intramolecular nitrone formation were also isolated.

引用

页码：2317 / 2324

页数：8

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