HYDROGEN-BONDING BETWEEN FREE FLUORIDE IONS AND WATER-MOLECULES - 2 X-RAY STRUCTURES

被引：33

作者：

EMSLEY, J ^{[1
]}

ARIF, M ^{[1
]}

BATES, PA ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

机构：

[1] QUEEN MARY COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 220卷

关键词：

D O I：

10.1016/0022-2860(90)80094-Z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structures of two copper complexes, [Cu(cyclam) (H2O)2]F2·4H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [Cu(en)2(H2O)2]F2·4H2O (en=ethylenediamine), are reported, in which the fluoride ions within their lattices are solvated by four water molecules attached by strong hydrogen bonds. The configurations of these and other "free" [F(H2O)n]- groupings are compared, and the strength of the hydrogen bonds discussed. © 1990.

引用

收藏

页码：1 / 12

页数：12

相关论文

共 39 条

[1] A STABLE BIS(THIOLATE) OF COPPER(II) WITH LONG AXIAL COPPER SULFUR LINKAGES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-[CU(CYCLAM)(SC6F5)2] [J].

ADDISON, AW ;

SINN, E .

INORGANIC CHEMISTRY, 1983, 22 (08) :1225-1228

[2]

ALLMANN R, 1978, ACTA CRYSTALLOGR A, V34, pS167

[3]

[Anonymous], 1974, LARGE MOL, DOI [10.1007/BFb0116438, DOI 10.1007/BFB0116438]

[4] HYDRATION OF HALIDE NEGATIVE IONS IN GAS PHASE .2. COMPARISON OF HYDRATION ENERGIES FOR ALKALI POSITIVE AND HALIDE NEGATIVE IONS [J].

ARSHADI, M ;

YAMDAGNI, R ;

KEBARLE, P .

JOURNAL OF PHYSICAL CHEMISTRY, 1970, 74 (07) :1475-&

[5]

BOEYENS JCA, 1968, ACTA CRYSTALL B-STRU, VB 24, P199

[6] STERIC EFFECTS ON THE SOLUTION CHEMISTRY OF NICKEL(II) COMPLEXES WITH N-MONOMETHYLATED 14-MEMBERED TETRAAZA MACROCYCLES - THE BLUE-TO-YELLOW CONVERSION AND THE OXIDATION AND REDUCTION BEHAVIOR [J].

CIAMPOLINI, M ;

FABBRIZZI, L ;

LICCHELLI, M ;

PEROTTI, A ;

PEZZINI, F ;

POGGI, A .

INORGANIC CHEMISTRY, 1986, 25 (23) :4131-4135

[7]

COTTON FA, 1988, ADV INORGANIC CHEM, pCH14

[8] RELATIVISTIC CALCULATION OF ANOMALOUS SCATTERING FACTORS FOR X-RAYS [J].

CROMER, DT ;

LIBERMAN, D .

JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (05) :1891-&

[9] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].

CROMER, DT ;

MANN, JB .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&

[10] VERY STRONG HYDROGEN-BONDING [J].

EMSLEY, J .

CHEMICAL SOCIETY REVIEWS, 1980, 9 (01) :91-124

← 1 2 3 4 →