HYDROGEN-BONDING BETWEEN FREE FLUORIDE IONS AND WATER-MOLECULES - 2 X-RAY STRUCTURES

被引：33

作者：

EMSLEY, J ^{[1
]}

ARIF, M ^{[1
]}

BATES, PA ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

机构：

[1] QUEEN MARY COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 220卷

关键词：

D O I：

10.1016/0022-2860(90)80094-Z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structures of two copper complexes, [Cu(cyclam) (H2O)2]F2·4H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [Cu(en)2(H2O)2]F2·4H2O (en=ethylenediamine), are reported, in which the fluoride ions within their lattices are solvated by four water molecules attached by strong hydrogen bonds. The configurations of these and other "free" [F(H2O)n]- groupings are compared, and the strength of the hydrogen bonds discussed. © 1990.

引用

页码：1 / 12

页数：12

共 39 条

[31] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].