IDENTIFICATION OF THE TRANSIENT BENZONITRILE N-SULFIDE BY FLASH-VACUUM PYROLYSIS AND NEUTRALIZATION-REIONIZATION MASS-SPECTROMETRY

被引：13

作者：

MAQUESTIAU, A

FLAMMANG, R

PLISNIER, M

WENTRUP, C

KAMBOURIS, P

PATON, MR

TERLOUW, JK

机构：

[1] MCMASTER UNIV,DEPT CHEM,HAMILTON L8S 4M1,ONTARIO,CANADA

[2] UNIV QUEENSLAND,DEPT CHEM,ST LUCIA,QLD 4067,AUSTRALIA

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1990年 / 100卷

关键词：

D O I：

10.1016/0168-1176(90)85090-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Using a combination of flash-vacuum pyrolysis and tandem mass spectrometry, it is shown that benzonitrile N-sulfide, 1, is a stable molecule in the diluted gas phase. This result is confirmed by neutralization-reionization experiments performed on a beam of the corresponding radical cations. © 1990.

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页码：477 / 488

页数：12

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