ENANTIO-DIFFERENTIATING HYDROGENATION OF 2-ALKANONES OVER ASYMMETRICALLY MODIFIED NICKEL-CATALYST AND ITS APPLICATION TO THE PREPARATION OF OPTICALLY PURE 2-ALKANOLS

被引：37

作者：

OSAWA, T ^{[1
]}

HARADA, T ^{[1
]}

TAI, A ^{[1
]}

机构：

[1] HIMEJI INST TECHNOL,HIMEJI,HYOGO 67122,JAPAN

来源：

JOURNAL OF CATALYSIS | 1990年 / 121卷 / 01期

关键词：

D O I：

10.1016/0021-9517(90)90212-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Enantio-differentiating hydrogenation of 2-alkanones over asymmetrically modified nickel catalyst was carried out with an average optical yield of about 80%. The factors affecting the optical yield of the reaction and their functions are discussed. A practical method for the optical enrichment of products of hydrogenation to optically pure 2-alkanols is also presented. © 1990.

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页码：7 / 17

页数：11

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