ENANTIO-DIFFERENTIATING HYDROGENATION OF 2-ALKANONES OVER ASYMMETRICALLY MODIFIED NICKEL-CATALYST AND ITS APPLICATION TO THE PREPARATION OF OPTICALLY PURE 2-ALKANOLS

被引：37

作者：

OSAWA, T ^{[1
]}

HARADA, T ^{[1
]}

TAI, A ^{[1
]}

机构：

[1] HIMEJI INST TECHNOL,HIMEJI,HYOGO 67122,JAPAN

来源：

JOURNAL OF CATALYSIS | 1990年 / 121卷 / 01期

关键词：

D O I：

10.1016/0021-9517(90)90212-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Enantio-differentiating hydrogenation of 2-alkanones over asymmetrically modified nickel catalyst was carried out with an average optical yield of about 80%. The factors affecting the optical yield of the reaction and their functions are discussed. A practical method for the optical enrichment of products of hydrogenation to optically pure 2-alkanols is also presented. © 1990.

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页码：7 / 17

页数：11

相关论文

共 32 条

[21] Investigations on the dependence of rotatory power on chemical constitution Part II The rotations of some secondary alcohols containing the isopropyl group [J].

Pickard, R ;

Kenyon, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1912, 101 :620-638

[22] Investigations on the dependence of rotatory power on chemical constitution. Part I. The rotations of the simplest secondary alcohols of the fatty series. [J].

Pickard, RH ;

Kenyon, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1911, 99 :45-72

[23] Investigations on the dependence of rotatory power on chemical constitution Part IV The rotations of the normal secondary alcohols of the formula C2H5CH(OH) R [J].

Pickard, RH ;

Kenyon, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1913, 103 :1923-1959

[24]

PICKARD RH, 1914, J CHEM SOC, V105, P115

[25]

REID EE, 1917, J AM CHEM SOC, V39, P1250

[26] STEREOCHEMICAL STUDIES OF THE HYDROGENATION WITH ASYMMETRICALLY MODIFIED NICKEL CATALYSTS - HYDROGENATION OF METHYL 2-ALKYL-3-OXOBUTYRATE [J].

TAI, A ;

WATANABE, H ;

HARADA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1979, 52 (05) :1468-1472

[27] STEREOCHEMICAL INVESTIGATION ON ASYMMETRICALLY MODIFIED RANEY-NICKEL CATALYST - MODE OF INTERACTION BETWEEN MODIFYING REAGENT AND SUBSTRATE IN THE ENANTIOFACE-DIFFERENTIATING PROCESS [J].

TAI, A ;

HARADA, T ;

HIRAKI, Y ;

MURAKAMI, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (05) :1414-1419

[28]

TAI A, 1988, 9 INT C CAT CAG, P1082

[29]

TAI A, 1986, TAILORED METAL CATAL, P265, DOI DOI 10.1007/978-94-009-5261-4_5

[30] USE OF SHIFT-REAGENT WITH DIASTEREOMERIC MTPA ESTERS FOR DETERMINATION OF CONFIGURATION AND ENANTIOMERIC PURITY OF SECONDARY CARBINOLS IN H-1 NMR-SPECTROSCOPY [J].

YAMAGUCHI, S ;

YASUHARA, F ;

KABUTO, K .

TETRAHEDRON, 1976, 32 (12) :1363-1367

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