REACTIONS OF BIVALENT-METAL IONS WITH BOROHYDRIDE IN AQUEOUS-SOLUTION FOR THE PREPARATION OF ULTRAFINE AMORPHOUS ALLOY PARTICLES

被引：137

作者：

SHEN, JY ^{[1
]}

LI, ZY ^{[1
]}

YAN, QJ ^{[1
]}

CHEN, Y ^{[1
]}

机构：

[1] NANJING UNIV, DEPT CHEM, NANJING 210008, PEOPLES R CHINA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 32期

关键词：

D O I：

10.1021/j100134a020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of Fe2+, Co2+, and Ni2+ with borohydride in aqueous solutions for the preparation of M-B (M = Fe, Co, and Ni) ultrafine amorphous alloy particles (UFAAP) have been studied. A reaction mechanism is proposed, according to which the composition of the M-B products can be predicted and some preparation parameters reported in this paper and in the literature can be explained. The products were characterized and confirmed to be UFAAP by Mossbauer spectroscopy, electron diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy.

引用

页码：8504 / 8511

页数：8

共 34 条

[1] REACTION OF SODIUM BOROHYDRIDE WITH NICKEL ACETATE IN AQUEOUS SOLUTION-A CONVENIENT SYNTHESIS OF AN ACTIVE NICKEL HYDROGENATION CATALYST OF LOW ISOMERIZING TENDENCY [J].

BROWN, CA ;

BROWN, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (07) :1003-&

[2] CATALYTIC HYDROGENATION .5. REACTION OF SODIUM BOROHYDRIDE WITH AQUEOUS NICKEL SALTS - P-1 NICKEL BORIDE, A CONVENIENT, HIGHLY ACTIVE NICKEL HYDROGENATION CATALYST [J].

BROWN, CA .

JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (06) :1900-+

[3] REACTION OF SODIUM BOROHYDRIDE WITH NICKEL ACETATE IN ETHANOL SOLUTION-A HIGHLY SELECTIVE NICKEL HYDROGENATION CATALYST [J].

BROWN, HC ;

BROWN, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (07) :1005-&

[4] FE-CO-B AMORPHOUS ALLOY POWDER BY CHEMICAL-REDUCTION [J].

CORRIAS, A ;

ENNAS, G ;

LICHERI, G ;

MARONGIU, G ;

MUSINU, A ;

PASCHINA, G ;

PICCALUGA, G ;

PINNA, G ;

MAGINI, M .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1988, 7 (04) :407-409

[5] CRYSTALLIZATION PROCESSES IN BORON-CONTAINING AND HYDROGEN-CONTAINING ULTRAFINE POWDERS [J].

DRAGIEVA, I ;

RUSEV, KR ;

STANIMIROVA, M .

JOURNAL OF THE LESS-COMMON METALS, 1990, 158 (02) :295-299

[6]

DUNCAN RN, 1984, PLAT SURF FINISH, V71, P49

[7] CONTINUOUS SERIES OF METASTABLE SOLID SOLUTIONS IN SILVER-COPPER ALLOYS [J].

DUWEZ, P ;

WILLENS, RH ;

KLEMENT, W .

JOURNAL OF APPLIED PHYSICS, 1960, 31 (06) :1136-1137

[8]

GUNTHERODT HJ, 1981, TOPICS APPLIED PHYSI, V46

[9] A STUDY OF FE-NI-B ULTRAFINE ALLOY PARTICLES PRODUCED BY REDUCTION WITH BOROHYDRIDE [J].

HU, Z ;

HSIA, YF ;

ZHENG, JG ;

SHEN, JY ;

YAN, QJ ;

DAI, LM .

JOURNAL OF APPLIED PHYSICS, 1991, 70 (01) :436-438

[10] FORMATION OF ULTRA-FINE AMORPHOUS POWDERS IN FE-M-B (M = TRANSITION-METAL) SYSTEMS BY CHEMICAL-REDUCTION METHOD AND THEIR THERMAL AND MAGNETIC-PROPERTIES [J].

INOUE, A ;

SAIDA, J ;

MASUMOTO, T .

METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1988, 19 (09) :2315-2331

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