CONCERNING THE DIASTEREOFACIAL SELECTIVITY OF ALDOL REACTIONS OF CHIRAL METHYL KETONE ENOLATES - EVIDENCE FOR REMOTE CHELATION IN THE BAFILOMYCIN ALDOL REACTION

被引：35

作者：

ROUSH, WR

BANNISTER, TD

WENDT, MD

机构：

[1] Department of Chemistry, Indiana University, Bloomington

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)61340-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Evidence is presented that the aldol reactions of the lithium enolates of 4 and 7 proceed preferentially by way of chelated transition structure 19.

引用

页码：8387 / 8390

页数：4

共 36 条

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