NON-STATISTICAL ENERGY PARTITIONING IN THE GAS-PHASE REACTIONS OF POLYATOMIC-MOLECULES

被引：8

作者：

MACDONALD, RG ^{[1
]}

SLOAN, JJ ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,DIV CHEM,OTTAWA K1A 0R6,ONTARIO,CANADA

来源：

CHEMICAL PHYSICS | 1979年 / 40卷 / 03期

关键词：

D O I：

10.1016/0301-0104(79)85144-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The internal energy distributions in the HF products from the reactions of F atoms with H2CO and HFCO have been determined via arrested-relaxation infrared chemiluminescence experiments. The results show that the HF vib-rotational levels are strongly excited and suggest that the HCO and FCO radical products are created with excitation in the ν1 (asymmetric stretch) and ν2 (bend) modes respectively. © 1979.

引用

页码：321 / 328

页数：8

共 32 条

[1] HOW ENERGY ACCUMULATION AND DISPOSAL AFFECT RATES OF REACTIONS [J].

BAUER, SH .

CHEMICAL REVIEWS, 1978, 78 (02) :147-184

[2] HF IR CHEMILUMINESCENCE - VIBRATIONAL AND ROTATIONAL ENERGY DISPOSAL FOR REACTIONS OF FLUORINE-ATOMS WITH FORMALDEHYDE, ACETALDEHYDE, BENZALDEHYDE, AND DIMETHYL ETHER [J].

BOGAN, DJ ;

SETSER, DW ;

SUNG, JP .

JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (09) :888-898

[3] HF INFRARED CHEMILUMINESCENCE - ENERGY DISPOSAL AND ROLE OF RADICAL FRAGMENT IN ABSTRACTION OF HYDROGEN FROM POLYATOMIC-MOLECULES BY F ATOMS [J].

BOGAN, DJ ;

SETSER, DW .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (02) :586-602

[4] INFRARED CHEMILUMINESCENCE AND ENERGY PARTITIONING FROM REACTIONS OF FLUORINE ATOMS WITH PRIMARY CARBON-HYDROGEN BONDS OF ALKANES, HALOGENATED METHANES, AND TETRAMETHYL SILANE [J].

CHANG, HW ;

SETSER, DW .

JOURNAL OF CHEMICAL PHYSICS, 1973, 58 (06) :2298-2309

[5] IR LASER-INDUCED ORGANIC-REACTIONS .1. IRRADIATION OF ETHYL-ACETATE WITH A PULSED CO2-LASER - SELECTIVE INDUCEMENT VS THERMAL-REACTION [J].

DANEN, WC ;

MUNSLOW, WD ;

SETSER, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (21) :6961-6963

[6] ANHARMONIC POTENTIAL CONSTANTS FOR CH STRETCHING IN HCO RADICAL [J].

DIXON, RN .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1969, 30 (02) :248-&

[7] INFRARED CHEMILUMINESCENCE AND ENERGY PARTITIONING FROM REACTIONS OF FLUORINE ATOMS WITH HYDRIDES OF CARBON, SILICON, OXYGEN, SULFUR, NITROGEN, AND PHOSPHORUS [J].

DUEWER, WH ;

SETSER, DW .

JOURNAL OF CHEMICAL PHYSICS, 1973, 58 (06) :2310-2320

[8] INFRARED DETECTION OF THE FORMYL RADICAL HCO [J].

EWING, GE ;

THOMPSON, WE ;

PIMENTEL, GC .

JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (03) :927-932

[9]

GRANT ER, 1977, LASER SPECTROSCOPY, V7

[10] THE 7500 TO 4500 A ABSORPTION SYSTEM OF THE FREE HCO RADICAL [J].

HERZBERG, G ;

RAMSAY, DA .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1955, 233 (1192) :34-54

← 1 2 3 4 →