IMIDO LIGAND REACTIVITY IN 4-CO-ORDINATE BIS(IMIDO) COMPLEXES OF MOLYBDENUM(VI)

被引：41

作者：

JOLLY, M ^{[1
]}

MITCHELL, JP ^{[1
]}

GIBSON, VC ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,SCI LABS,S RD,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 07期

关键词：

D O I：

10.1039/dt9920001329

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The four-co-ordinate complexes Mo(NR)2(OBu(t)), (R = Bu(t) or 2,6-Pr(i)2C6H3) undergo imido ligand exchange reactions with benzaldehyde, amines and dioxygen;the reaction of Mo(NR)2(OBu(t))2 (R = 2,6-Pr(i)2C6H3) with phenyl isocyanate, however, leads to the formation of a bis(metallacycle) complex.

引用

页码：1329 / 1330

页数：2

共 19 条

[1] A COMBINED TRANSIENT-RESPONSE AND TEMPERATURE-PROGRAMMED DESORPTION TECHNIQUE USED IN THE AMMOXIDATION OF 3-PICOLINE OVER A V2O5 CATALYST
ANDERSSON, A
[J]. JOURNAL OF CATALYSIS, 1986, 100 (02) : 414 - 428
[2] BASHALL A, UNPUB
[3] TETRAKIS(DIMETHYLAMIDO) COMPLEXES OF OXOTUNGSTEN(VI) AND (PHENYLIMIDO)TUNGSTEN(VI)
BERG, DM
SHARP, PR
[J]. INORGANIC CHEMISTRY, 1987, 26 (18) : 2959 - 2962
[4] ASPECTS OF SELECTIVE OXIDATION AND AMMOXIDATION MECHANISMS OVER BISMUTH MOLYBDATE CATALYSTS
BURRINGTON, JD
GRASSELLI, RK
[J]. JOURNAL OF CATALYSIS, 1979, 59 (01) : 79 - 99
[5] DI-TERT-BUTOXYBIS(ARYLIMIDO)MOLYBDENUM(VI) COMPOUNDS, [MO(O-T-BU)2(NAR)(MU-NAR)]2, WHERE AR = PHENYL AND P-TOLYL
CHISHOLM, MH
FOLTING, K
HUFFMAN, JC
RATERMANN, AL
[J]. INORGANIC CHEMISTRY, 1982, 21 (03) : 978 - 982
[6] MONOMERIC (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM IMIDO COMPOUNDS - SYNTHESIS, STRUCTURE, AND REACTIVITY
GLUECK, DS
WU, JX
HOLLANDER, FJ
BERGMAN, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (06) : 2041 - 2054
[7] SELECTIVE OXIDATION AND AMMOXIDATION OF OLEFINS BY HETEROGENEOUS CATALYSIS
GRASSELLI, RK
[J]. JOURNAL OF CHEMICAL EDUCATION, 1986, 63 (03) : 216 - 221
[8] IMIDO LIGAND-EXCHANGE AT A MOLYBDENUM(V) CENTER
HOGARTH, G
KONIDARIS, PC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 399 (1-2) : 149 - 152
[9] Keulks G. W., 1979, ADV CATAL, V27, P183
[10] UNPRECEDENTED FORMATION OF A DIHYDROPYRIDINE DIMER FROM CARBON-MONOXIDE AND PYRIDINE MEDIATED BY A DIOXODIMESITYLMOLYBDENUM(VI) COMPLEX
LAI, R
LEBOT, S
FAURE, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 336 (1-2) : C5 - C8

← 1 2 →