ILWENSISAPONIN-A, ILWENSISAPONIN-B, ILWENSISAPONIN-C, AND ILWENSISAPONIN-D - TRITERPENE SAPONINS FROM SCROPHULARIA-ILWENSIS

被引：19

作者：

CALIS, I ^{[1
]}

ZOR, M ^{[1
]}

BASARAN, AA ^{[1
]}

WRIGHT, AD ^{[1
]}

STICHER, O ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL, DEPT PHARM, CH-8092 ZURICH, SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1993年 / 76卷 / 03期

关键词：

D O I：

10.1002/hlca.19930760322

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From the aerial parts of Scrophularia ilwensis, four new triterpene saponins, ilwensisaponins A-D (1-4) were isolated. The structures of the compounds were elucidated using chemical and spectral data as 13beta,28-epoxy-3-beta {{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}olean-11-en-23-ol (1), 3-beta-{{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}oleana-11,13(18)-diene-23,28-diol (2), 3-beta-{{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}-11alpha-methoxyolean-12-ene-23,28-diol (3), and 3-beta-{{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}olean-12-ene-11alpha,23,28-triol (4).

引用

页码：1352 / 1360

页数：9

共 13 条

[1]

ANIL H, 1980, J MED PHARM, V4, P1

[2] PHENYLPROPANOID GLYCOSIDES ISOLATED FROM SCROPHULARIA-SCOPOLII [J].

CALIS, I ;

GROSS, GA ;

STICHER, O .

PHYTOCHEMISTRY, 1987, 26 (07) :2057-2061

[3] 2 PHENYLPROPANOID GLYCOSIDES FROM SCROPHULARIA-SCOPOLII [J].

CALIS, I ;

GROSS, GA ;

STICHER, O .

PHYTOCHEMISTRY, 1988, 27 (05) :1465-1468

[4] ISOLATION AND STRUCTURE ELUCIDATION OF 2 HIGHLY ACYLATED IRIDOID DIGLYCOSIDES FROM SCROPHULARIA-SCOPOLII [J].

CALIS, I ;

GROSS, GA ;

WINKLER, T ;

STICHER, O .

PLANTA MEDICA, 1988, (02) :168-170

[5]

CALIS I, IN PRESS J NAT PROD

[6]

CALUS I, 1991, PLANTA MED S2, V57, pA68

[7]

DODDRELL DM, 1974, TETRAHEDRON LETT, P2381

[8]

ISHII H, 1977, TETRAHEDRON LETT, P1227, DOI 10.1016/S0040-4039(01)92982-X

[9] SAPONINS FROM VERBASCUM-NIGRUM [J].

KLIMEK, B ;

LAVAUD, C ;

MASSIOT, G .

PHYTOCHEMISTRY, 1992, 31 (12) :4368-4370

[10] TRITERPENE SAPONINS FROM VERBASCUM-SONGARICUM [J].

SEIFERT, K ;

PREISS, A ;

JOHNE, S ;

SCHMIDT, J ;

LIEN, NT ;

LAVAUD, C ;

MASSIOT, G .

PHYTOCHEMISTRY, 1991, 30 (10) :3395-3400

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