POLYDISPERSITY OF AOT DROPLETS MEASURED BY TIME-RESOLVED FLUORESCENCE QUENCHING

被引:43
作者
ALMGREN, M [1 ]
JOHANNSSON, R [1 ]
ERIKSSON, JC [1 ]
机构
[1] ROYAL INST TECHNOL,DEPT PHYS CHEM,S-10044 STOCKHOLM 70,SWEDEN
关键词
D O I
10.1021/j100135a010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The size and polydispersity of AOT water/oil microemulsions were measured by time-resolved fluorescence quenching. From the measured volume polydispersity the radius polydispersity was derived and calculated. An average polydispersity of 15.7% was obtained. No trends in polydispersity values at different droplet sizes or different solvent chain lengths were observed. The polydispersity values obtained are compared with values obtained by a new approach to theoretically estimate the polydispersity, and approximate values for the interfacial tension, gamma(infinity), of the planar oil/water interface and the interfacial bending constant, K, were computed.
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页码:8590 / 8594
页数:5
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