SYNTHESIS AND REACTIVITY OF CHIRAL RHENIUM AMINE AND AMIDE COMPLEXES OF THE FORMULAS [(ETA-5-C5H5)RE(NO)(PPH3)(NHRR')]+TFO- AND (ETA-5-C5H5)RE(NO)(PPH3)(NRR')

被引：27

作者：

DEWEY, MA ^{[1
]}

BAKKE, JM ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1021/om00118a083

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of racemic and optically active (η5-C5H5)Re(NO)(PPh3)(OTf) with primary and secondary amines give the amine complexes [(η5-C5H5)Re(NO)-(PPh3)(NHRRʹ)]+TfO- with retention of configuration at rhenium. These react with n-BuLi to give amide complexes (η5-C5H5)Re(NO)(PPh3)(NRRʹ) that contain an unusually basic and nucleophilic nitrogen. © 1990, American Chemical Society. All rights reserved.

引用

页码：1349 / 1351

页数：3

共 18 条

[11] A GENERAL-METHOD FOR THE SELECTIVE BINDING AND ACTIVATION OF ONE ALDEHYDE ENANTIOFACE - SYNTHESIS AND REACTIVITY OF RHENIUM ALDEHYDE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-2-RCH=O)]+PF6- [J].