SYNTHESIS AND CHARACTERIZATION OF IRON DERIVATIVES OF DIHYDROLIPOIC ACID AND DIHYDROLIPOAMIDE

被引：9

作者：

BONOMI, F

PAGANI, S

CARIATI, F

POZZI, A

CRISPONI, G

CRISTIANI, F

NURCHI, V

RUSSO, U

ZANONI, R

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM INORGAN & METALLORGAN,VIA VENEZIAN 21,I-20133 MILAN,ITALY

[2] UNIV MILAN,DIPARTIMENTO SCI MOLEC AGROALIMENTARI,I-20133 MILAN,ITALY

[3] UNIV CAGLIARI,DIPARTIMENTO CHIM & TECNOL INORGAN METALLORGAN,I-09100 CAGLIARI,ITALY

[4] UNIV PADUA,DIPARTIMENTO CHIM INORGAN METALLORGAN ANAL,I-35100 PADUA,ITALY

[5] UNIV ROME LA SAPIENZA,DIPARTIMENTO CHIM,I-00100 ROME,ITALY

来源：

INORGANICA CHIMICA ACTA | 1992年 / 195卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)83857-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and properties of physiologically relevant complexes of iron(II) and iron(III) with dihydrolipoic acid and dihydrolipoamide are described. Data obtained from measurements of the magnetic properties of the compounds are discussed along with results obtained by vibrational, electronic, EPR and Mossbauer spectroscopy. While iron(III) compounds present a low-spin, d5 configuration, iron(II) compounds present an intermediate spin state, S = 1, d6 configuration.

引用

页码：109 / 115

页数：7

共 28 条

[1] POWDER LINE SHAPES IN ELECTRON PARAMAGNETIC RESONANCE SPECTRA OF HIGH-SPIN FERRIC COMPLEXES [J].