ON CA3IRCUO6

被引：31

作者：

TOMASZEWSKA, A ^{[1
]}

MULLERBUSCHBAUM, H ^{[1
]}

机构：

[1] UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,W-2300 KIEL 1,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 03期

关键词：

CALCIUM; IRIDIUM; COPPER; OXIDE; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19936190318

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of Ca3IrCuO6 were prepared by a flux technique and investigated by single crystal X-ray work. It crystallizes with monoclinic symmetry, space group C2h6-C12/c1; a = 9.032, b = 9.295, c = 6.466 angstrom, beta = 91.35-degrees, Z = 4. Ca3IrCuO6 is isotypic to Sr3IrCuO6. The square planare CuO4 polygones show probably a slightly deficit accompanied by an adequate part of iridium in the oxydation state Ir5+.

引用

页码：534 / 536

页数：3

共 9 条

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