CYCLOPALLADATED COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF DI-MU-CHLORO-BIS([2,6-DIMETHYL-N-(BENZYLIDENE)PHENYLAMINATO-C2',N]PALLADIUM(II))

被引：38

作者：

CRISPINI, A ^{[1
]}

DEMUNNO, G ^{[1
]}

GHEDINI, M ^{[1
]}

NEVE, F ^{[1
]}

机构：

[1] UNIV CALABRIA,DIPARTIMENTO CHIM,I-87030 ARCAVACATA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 427卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80078-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray crystal structure of the cyclometallated palladium(II) complex [{Pd(L2)(mu-Cl)}2], L2 = 2,6-dimethyl-N-(benzylidene)phenylaminate, is described. Crystals were orthorhombic, space group Pna2(1) with a = 17.307(3) angstrom, b = 17.732(4) angstrom, c = 9.075 angstrom, Z = 4, U = 2785.0(10) angstrom3. The palladated dimer, with asymmetrically bridging chlorine atoms, exhibits a Pd2Cl2 unit folded at 36.7(1)-degrees and a non-bonding Pd ... Pd separation of 3.425(1) angstrom.

引用

收藏

页码：409 / 414

页数：6

相关论文

共 12 条

[1] REACTIONS OF CYCLOPALLADATED BENZYLIDENE-ANILINE SCHIFF-BASE COMPLEXES - SELECTIVE SYNTHESIS OF 2'-SUBSTITUTED SCHIFF-BASE DERIVATIVES AND THE X-RAY CRYSTAL-STRUCTURE OF THE DIMER [PD(MU-OAC)(5'-OCH3-C6H3CH=NC6H4-4-CH3)]2 [J].

ALBINATI, A ;

PREGOSIN, PS ;

RUEDI, R .

HELVETICA CHIMICA ACTA, 1985, 68 (07) :2046-2061

[2] CYCLOPALLADATED COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF DI-MU-CHLORO-BIS[2',6'-DIMETHYLAZOBENZENATO-C2,N2)PALLADIUM(II)] [J].

ARMENTANO, S ;

CRISPINI, A ;

DEMUNNO, G ;

GHEDINI, M ;

NEVE, F .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :966-968

[3] STRUCTURAL SYSTEMATICS OF THE ISOMERIC DI-MU-CHLOROBIS(N,N-DIALKYLBENZYLAMINE-2,C,N)DIPALLADIUM(II) COMPLEXES - THE CRYSTAL-STRUCTURES OF THE ORTHO-METHOXY, META-METHOXY AND PARA-METHOXY SUBSTITUTED COMPLEXES [J].

BARR, N ;

DYKE, SF ;

SMITH, G ;

KENNARD, CHL ;

MCKEE, V .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 288 (01) :109-117

[4] DI-MU-CHLORO-BIS[(BENZOPHENONE PHENYLHYDRAZONIDO-N,C)PALLADIUM(II)] [J].

CLARK, PW ;

DYKE, SF ;

SMITH, G ;

KENNARD, CHL ;

WHITE, AH .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 :1742-1745

[5] STRUCTURE OF DI-MU-ACETATO-(O,O')-BIS[N-(ALPHA-PHENYLBENZYLIDENE)CYCLOHEXYLAMINE-N,C]-DIPALLADIUM(II) [J].

GAYOSO, M ;

ALONSO, M ;

VILA, JM ;

RIVERO, EB ;

HILLER, W ;

STRAHLE, J .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :929-931

[6] TRANSITION-METALS COMPLEXED TO ORDERED MESOPHASES .6. SYNTHESIS, MESOMORPHIC BEHAVIOR AND X-RAY MOLECULAR-STRUCTURE OF THE CYCLOPALLADATED DIMER [(L)PDCL]2 (HL=N-(4-METHOXYBENZYLIDENE)-4'-BUTYLANILINE) [J].

GHEDINI, M ;

ARMENTANO, S ;

DEMUNNO, G ;

CRISPINI, A ;

NEVE, F .

LIQUID CRYSTALS, 1990, 8 (05) :739-744

[7] SIGNIFICANCE TESTS ON CRYSTALLOGRAPHIC R FACTOR [J].

HAMILTON, WC .

ACTA CRYSTALLOGRAPHICA, 1965, 18 :502-&

[8] PARST - A SYSTEM OF FORTRAN ROUTINES FOR CALCULATING MOLECULAR-STRUCTURE PARAMETERS FROM RESULTS OF CRYSTAL-STRUCTURE ANALYSES [J].

NARDELLI, M .

COMPUTERS & CHEMISTRY, 1983, 7 (03) :95-98

[9] DIRECTED CLEAVAGE OF CARBON TIN BONDS BY PALLADIUM [J].

SUGGS, JW ;

LEE, KS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 299 (03) :297-309

[10] SYNTHESIS OF CYCLOMETALLATED COMPLEXES OF PD(II) - THE X-RAY CRYSTAL-STRUCTURE OF DI-MU-BROMO-BIS[N-(3,4-DIMETHOXYBENZYLIDENE)CYCLOHEXYLAMINATO-C6,N]DIPALLADIUM(II) [J].

VILA, JM ;

GAYOSO, M ;

PEREIRA, MT ;

ROMAR, A ;

FERNANDEZ, JJ ;

THORNTONPETT, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 401 (03) :385-394