REACTIONS OF EPISULFONIUM IONS FROM THE SULFENYLATION OF ALKENES AND FROM PHENYLTHIO MIGRATION - KINETIC VS THERMODYNAMIC CONTROL

被引：18

作者：

BIRD, P

EAMES, J

FALLIS, AG

JONES, RVH

RODDIS, M

STURINO, CF

OSULLIVAN, S

WARREN, S

WESTWELL, MS

WORRALL, J

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

[3] ZENECA FINE CHEM MFG ORG,GRANGEMONTH FK3 8XG,SCOTLAND

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 11期

基金：

英国工程与自然科学研究理事会; 加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0040-4039(95)00110-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The formation of the same cyclic ethers from the sulfenylation of unsaturated alcohols and from acid catalysed phenylthio migration on diols via the same intermediate can be explained by kinetic and thermodynamic control. Both reactions are synthetically useful. A result from a previous Tetrahedron Letter is corrected.

引用

页码：1909 / 1912

页数：4

共 12 条

[1] TRANSFORMATION OF CYCLIC ALPHA-PHENYLTHIO ALDEHYDES BY STEREOSELECTIVE ALDOL REACTIONS AND PHENYLTHIO MIGRATION INTO SPIROCYCLIC LACTONES AND ETHERS, AND E-ALLYLIC ALCOHOLS WITH 1,4-RELATED CHIRAL CENTERS [J].