BRIDGEHEAD RADICALS

被引:52
作者
WALTON, JC
机构
[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
[2] UNIV ST ANDREWS,ORGAN CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
关键词
D O I
10.1039/cs9922100105
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rigid structures of bridgehead radicals (such as adamantyl) give them properties different from those of acyclic tertiary radicals and make them a considerable theoretical importance. Calculations and spectroscopic techniques (principally EPR) are important tools in exploring this fascinating group of reactive intermediates.
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页码:105 / 112
页数:8
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