THE BIOSYNTHETIC ORIGIN OF THE CENTRAL ONE-CARBON UNIT OF PHENYLPHENALENONES IN ANIGOZANTHOS-PREISSII

被引：33

作者：

HOLSCHER, D ^{[1
]}

SCHNEIDER, B ^{[1
]}

机构：

[1] INST BIOCHEM PFLANZEN,D-06120 HALLE,GERMANY

来源：

NATURAL PRODUCT LETTERS | 1995年 / 7卷 / 03期

关键词：

HYDROXYANIGORUFONE; PHENYLPHENALENONES; BIOSYNTHESIS; ANIGOZANTHOS PREISSII; HAEMODORACEAE;

D O I：

10.1080/10575639508043208

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The biosynthetic origin of all 19 carbon atoms of the phenylphenalenones was established by C-13 NMR analysis of hydroxyanigorufone, isolated from cultured roots of Anigozanthos preissii after administration of C-13 labelled precursors. High incorporation of C-2 of [2-C-13]acetate into the central carbon atom for the first time unambiguously proved the origin of this C-1 unit of phenylphenalenones.

引用

页码：177 / 182

页数：6

共 16 条

[1]

Cooke R G, 1981, Fortschr Chem Org Naturst, V40, P153

[2] COLORING MATTERS OF AUSTRALIAN PLANTS .18. CONSTITUENTS OF ANIGOZANTHOS-RUFUS [J].