ELECTRON-DEFICIENT VANADIUM ALKYL COMPLEXES - SYNTHESIS AND MOLECULAR-STRUCTURE OF THE VANADIUM(III) DINITROGEN COMPLEX [(ME3CCH2)3V]2(MU-N2)

被引：59

作者：

BUIJINK, JKF ^{[1
]}

MEETSMA, A ^{[1
]}

TEUBEN, JH ^{[1
]}

机构：

[1] UNIV GRONINGEN,DEPT CHEM,GRONINGEN CTR CATALYSIS & SYNTH,NIJENBORGH 4,9747 AG GRONINGEN,NETHERLANDS

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 06期

关键词：

D O I：

10.1021/om00030a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The vanadium(III) dinitrogen-bridged complex [(Me3CCH2)3V]2(mu-N2) (1), obtained from reaction Of VCl3(THF)3 and Me3CCH2Li under nitrogen, is converted to the vanadium(V) oxo complex OV(CH2CMe3)3 (3) by reaction with styrene oxide. Both 1 and 3 decompose at ambient temperature to give neopentane and species which are active in the ring-opening metathesis polymerization of norbornene.

引用

页码：2004 / 2005

页数：2

共 23 条

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