MOLECULAR-STRUCTURE OF COPPER NITRITO COMPLEX AS THE REACTION INTERMEDIATE OF DISSIMILATORY REDUCTION OF NO2-

被引：34

作者：

KOMEDA, N

NAGAO, H

ADACHI, GY

SUZUKI, M

UEHARA, A

TANAKA, K

机构：

[1] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN

[2] KANAZAWA UNIV, FAC SCI, DEPT CHEM, KANAZAWA 92011, JAPAN

[3] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 09期

关键词：

D O I：

10.1246/cl.1993.1521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical reduction of NO2- by [Cu(tpa)(H2O)](ClO4)2 (tpa = tris[(2-pyridyl)methyl]amine) under the controlled potential electrolysis at -0.40 V (vs. Ag/AgCl) in H2O (pH 7.0) catalytically produced N2O with concomitant NO evolution. As the precursor of NO evolution, [Cu(tpa)(ONO)]PF6 was characterized by X-ray crystallography.

引用

页码：1521 / 1524

页数：4