EUROPIUM ISOTOPE-SEPARATION IN THE HC1 HDEHP EXTRACTION SYSTEM

被引:12
作者
DEMBINSKI, W
MIODUSKI, T
机构
[1] Institute of Nuclear Chemistry and Technology, Warsaw
来源
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS | 1995年 / 199卷 / 02期
关键词
D O I
10.1007/BF02162479
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The Eu-153/151 isotope separation factor (q) for the Eu(II)/Eu(III) chemical exchange in the liquid-liquid extraction system, containing Eu(III) in di(2-ethylhexyl)phosphoric acid (HDEHP) and Eu(II) in water acidified with hydrochloric acid, was found to be 0.9993 +/- 0.0002 (2sigma) for the single stage. Some theoretical aspects of separation of the Eu isotopes are discussed. The decisive role of the electron exchange reaction adn complexation by the counter-ion in the aqueous phase is emphasized.
引用
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页码:159 / 171
页数:13
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