REACTIONS LEADING TO FORMATION AND CLEAVAGE OF METAL METAL AND METAL MU-PHOSPHIDO BONDS IN BINUCLEAR MOLYBDENUM AND TUNGSTEN COMPLEXES - STRUCTURAL-ANALYSES OF W2(CO)8(MU-PPH2)2 AND ITS 2-ELECTRON REDUCTION PRODUCT, [LI(THF)3]2[W2(CO)8(MU-PPH2)2]

被引：47

作者：

SHYU, SG

CALLIGARIS, M

NARDIN, G

WOJCICKI, A

机构：

[1] UNIV TRIESTE,DIPARTIMENTO SCI CHIM,I-34127 TRIESTE,ITALY

[2] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1987年 / 109卷 / 12期

关键词：

D O I：

10.1021/ja00246a018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：3617 / 3625

页数：9

共 60 条

[31] CONTROLLING THE NUMBER OF METAL SITES TO WHICH A DI(TERTIARY PHOSPHINE) COORDINATES IN GROUP-6 METAL-CARBONYLS [J].

KEITER, RL ;

SUN, YY ;

BRODACK, JW ;

CARY, LW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (10) :2638-2641

[32] SYNTHESIS AND P-31 NMR CHARACTERIZATION OF [W2(CO)10PPH2]-, [W2(CO)9(PPH2H)PPH2]-, [W2(CO)8(PPH2)2]2-, AND W2(CO)8(PPH2)2 [J].

KEITER, RL ;

MADIGAN, MJ .

ORGANOMETALLICS, 1982, 1 (02) :409-411

[33] LINKED BIS(MU-PHOSPHIDO) AND RELATED LIGANDS FOR METALLIC CLUSTERS .5. EVIDENCE FOR A HIGHLY SELECTIVE BACKSIDE ATTACK BY STRONG NUCLEOPHILES ON A MU-PHOSPHIDO CENTER [J].

KYBA, EP ;

DAVIS, RE ;

CLUBB, CN ;

LIU, ST ;

PALACIOS, HOA ;

MCKENNIS, JS .

ORGANOMETALLICS, 1986, 5 (05) :869-877

[34] ORGANOMETAL CHEMISTRY .13. PREPARATION AND STRUCTURAL DETERMINATION OF MU-ALKYLIDENE (OCTACARBONYL) DITUNGSTEN COMPLEX [J].

LEVISALLES, J ;

RUDLER, H ;

DAHAN, F ;

JEANNIN, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 187 (02) :233-242

[35] COMPARISON OF 2 ISOMORPHOUS STRUCTURES - DI-MU-DIETHYLPHOSPHIDO-BIS-(TETRACARBONYLMOLYBDENUM) AND DI-MU-DIETHYLPHOSPHIDO-BIS-(TETRACARBONYLTUNGSTEN) [J].

LINCK, MH ;

NASSIMBE.LR .

INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1973, 9 (10) :1105-1113

[36]

LINCK MH, 1973, CRYST STRUCT COMMUN, V3, P379

[37] CARBON-CARBON BOND FORMATION ON MULTISITE-BOUND UNSATURATED LIGANDS - SYNTHESIS OF MU-2-ETA-2-ALLENYL COMPLEXES VIA CARBENE ADDITION TO THE BINUCLEAR ACETYLIDES RU2(CO)6(MU-2-ETA-2-C=CR)(MU-PPH2) [J].

NUCCIARONE, D ;

TAYLOR, NJ ;

CARTY, AJ .

ORGANOMETALLICS, 1986, 5 (06) :1179-1187

[38]

PERRIN DD, 1966, PURIFICATION LABORAT

[39] BRIDGE VS TERMINAL PROTONATION OF ISOSTRUCTURAL MO-PT AND W-PT HETEROBIMETALLIC COMPOUNDS [J].

POWELL, J ;

SAWYER, JF ;

SMITH, SJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (19) :1312-1313

[40]

ROBERTS DA, 1982, COMPREHENSIVE ORGANO, pCH40

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