ETHER-SOLUBLE TI(0) AND BIS(ETA-6-ARENE)TITANIUM(0) COMPLEXES FROM THE REDUCTION OF TICL4 WITH TRIETHYLHYDROBORATE

被引：49

作者：

BONNEMANN, H

KORALL, B

机构：

[1] Max‐Planck‐Institut für Kohlenforschung, Mülheim An Der Ruhr, D-W-4330

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 11期

关键词：

D O I：

10.1002/anie.199214901

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first preparation of bis (eta6-arene)titanium(0) complexes was achieved by reduction of TiCl4 with the borate [BEt3H]- in the appropriate arene solvent. In contrast the same reduction in THF leads to soluble "TiH2", which loses H-2 when dried to give a substance which can be formulated as Ti . 05 THF with various amounts of residual hydrogen. X-ray photoelectron spectroscopy and EXAFS analysis support the assumed oxidation state of zero for the titanium.

引用

页码：1490 / 1492

页数：3

共 13 条

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