AROMATIC GALLIUM HETEROCYCLES - SYNTHESIS OF THE FIRST GALLATABENZENE

被引：32

作者：

ASHE, AJ

ALAHMAD, S

KAMPF, JW

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor, Michigan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 12期

关键词：

ARENE COMPLEXES; GALLIUM COMPOUNDS; HETEROCYCLES; MANGANESE COMPOUNDS;

D O I：

10.1002/anie.199513571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deprotonation of the conjugate acid 2 led to the first gallatabenzene 1. The acidity of 2 and the low‐field shift of the NMR signals of the ring protons of 1 relative to the corresponding properties of cyclohexadienide suggest that 1 has aromatic character. The heterocycle of 1 can function as a ligand and was coordinated to a Mn(CO)3 fragment. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1357 / 1359

页数：3

共 26 条

[1] BIS(1-SUBSTITUTED-BORABENZENE)IRON COMPLEXES
ASHE, AJ
MEYERS, E
SHU, P
VONLEHMANN, T
BASTIDE, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (23) : 6865 - 6866
[2] 1-PHENYLBORABENZENE ANION
ASHE, AJ
SHU, P
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (07) : 1804 - &
[3] ACIDITIES OF CARBON AND NITROGEN ACIDS - THE AROMATICITY OF THE CYCLOPENTADIENYL ANION
BORDWELL, FG
DRUCKER, GE
FRIED, HE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (03) : 632 - 635
[4] CRYSTAL AND MOLECULAR STRUCTURE OF PI-CYCLOHEXADIENYLMANGANESE TRICARBONYL
CHURCHILL, MR
SCHOLER, FR
[J]. INORGANIC CHEMISTRY, 1969, 8 (09) : 1950 - +
[5] Cowley A. H., 1994, ANGEW CHEM, V106, P1429
[6] REACTIONS OF A BULKY ARYLGALLIUM DICHLORIDE WITH ORGANOMETALLIC MONOANIONS - FORMATION OF A DIGALLOXANE WITH ORGANOMETALLIC SUBSTITUENTS
COWLEY, AH
DECKEN, A
OLAZABAL, CA
NORMAN, NC
[J]. INORGANIC CHEMISTRY, 1994, 33 (16) : 3435 - 3437
[7] REACTIVITY OF A PHOSPHANYLCARBENE (LAMBDA(5)-PHOSPHAACETYLENE) WITH LEWIS-ACIDS - X-RAY CRYSTAL-STRUCTURES OF THE FIRST CARBENE-GALLANE COMPLEX AND C-GALLYL-SUBSTITUTED PHOSPHORUS YLIDE
COWLEY, AH
GABBAI, FP
CARRANO, CJ
MOKRY, LM
BOND, MR
BERTRAND, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (05): : 578 - 580
[8] COWLEY AH, 1994, ANGEW CHEM INT EDIT, V33, P1370, DOI 10.1002/anie.199413701
[9] COWLEY AH, 1994, ANGEW CHEM, V106, P584
[10] NOVEL AROMATIC BORON HETEROCYCLE AS LIGAND IN A TRANSITION METAL PI-COMPLEX
HERBERIC.GE
GREISS, G
HEIL, HF
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1970, 9 (10) : 805 - &

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