REACTIONS OF A BULKY ARYLGALLIUM DICHLORIDE WITH ORGANOMETALLIC MONOANIONS - FORMATION OF A DIGALLOXANE WITH ORGANOMETALLIC SUBSTITUENTS

被引:30
作者
COWLEY, AH [1 ]
DECKEN, A [1 ]
OLAZABAL, CA [1 ]
NORMAN, NC [1 ]
机构
[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND
关键词
D O I
10.1021/ic00094a001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of the bulky arylgallium dichloride Ar'GaCl2 OV = 2,4,6-t-Bu3C6H2) with 2.2 equiv of Na[Co(CO)4] in Et2O solution affords the intermetallic derivative [Ga(Ar'){Co(CO4)2] (1). Interestingly, the corresponding reaction of Ar'GaCl2 With Na[Mn(CO)5] in Et2O solution affords a mixed crystal of the first digalloxane, [Ga(Ar'){Mn-(CO)5}]2O (2) and [Ga(Ar)(Cl){Mn(CO)5}] (3). The structures of 1-3 have been established by X-ray crystallography.
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页码:3435 / 3437
页数:3
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