SIMPLE METHODS OF CIS-HYDROXYLATION OF F-ALKYLETHYLENES

被引：15

作者：

AYARI, A

SZONYI, S

ROUVIER, E

CAMBON, A

机构：

[1] Laboratoire de Chimie Organique du Fluor, Université de Nice, 06034 Nice Cedex, Parc Valrose

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 50卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)82179-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of 2-F-alkyl ethane-1,2 diols from F-alkyl ethylenes and permanganates is reported. Among the three methods tested and described, one, carried out in a homogeneous non aqueous phase (CH2Cl2) and with a stoechiometric amount of Phase Transfer Catalysis Agent (PCTA) gave the best yields ({reversed tilde equals}80%). © 1990.

引用

页码：67 / 75

页数：9

共 27 条

[1]

AMIMOTO Y, 1978, Patent No. 7884909

[2]

BUSHAN V, 1984, SYNTHESIS-STUTTGART, P431

[3] NEW METHODS OF PREPARING F-ALKYL OXIRANES FROM 2-BROMO-2-F-ALKYLETHYL ACETATES AND 2-BROMO-2-F-ALKYLETHANOLS [J].