EQUILIBRIA AND KINETICS OF CYCLOHEXENYL-CYCLOPENTENYL CATION REARRANGEMENT

被引:31
作者
SORENSEN, TS
机构
[1] Department of Chemistry, University of Calgary, Calgary, Alberta
关键词
D O I
10.1021/ja01051a037
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cyclopentenyl and cyclohexenyl cations have been observed in equilibrium with one another. The kinetics of the approach to equilibrium and the equilibrium constants have been measured in eleven different acid solvents for four series of these ions. An attempt is made to rationalize the marked stability of cyclopentenyl cations compared to the cyclohexenyl analogs. © 1969, American Chemical Society. All rights reserved.
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页码:6398 / &
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