RING PUCKERING MOTION IN INDAN - A MICROWAVE SPECTROSCOPY STUDY

被引：22

作者：

CAMINATI, W ^{[1
]}

DAMIANI, D ^{[1
]}

CORBELLI, G ^{[1
]}

FAVERO, LB ^{[1
]}

机构：

[1] CNR, IST SPETTROSCOPIA MOLEC, I-40126 BOLOGNA, ITALY

来源：

MOLECULAR PHYSICS | 1992年 / 75卷 / 04期

关键词：

D O I：

10.1080/00268979200100651

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

O+O- doubling due to the double minimum potential of the ring puckering has been observed in the rotational spectrum of indan. The barrier to inversion has been determined. The value of 433.5(1) cm-1 has been obtained, extremely low with respect to the value of 1979 cm-1 from the far infrared (Smithson, T. L., Duckett, J. A., and Wieser, H., 1984, J. phys. Chem., 88, 1102) and single vibronic level fluorescence spectra (Hassan, K. H., and Hollas, J. M., 1991, J. molec. Spectrosc., 147, 100).

引用

页码：857 / 865

页数：9

共 22 条

[1]

[Anonymous], 1977, VIBRATIONAL SPECTRA

[2]

[Anonymous], UNPUB

[3] VIBRATION-ROTATION INTERACTION IN MICROWAVE SPECTRUM OF CYCLOPENTENE [J].