STRUCTURAL ASSIGNMENT OF (SIGMA-PI) PALLADIUM COMPLEXES

被引：8

作者：

GOGOLL, A

GRENNBERG, H

机构：

[1] Department of Organic Chemistry, University of Uppsala, Uppsala, S-751 21

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1993年 / 31卷 / 10期

关键词：

2D-NMR; C-13; H-1-INVERSE CORRELATION; F-19-INVERSE CORRELATION; HMQC; P.E.COSY; NOESY; ROESY; SELECTIVE INEPT; PALLADIUM COMPLEXES; CHELATING LIGANDS; MOLECULAR MODELING; AM1;

D O I：

10.1002/mrc.1260311014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of (sigma-pi)palladium complexes derived from cyclooctadiene were investigated by H-1, C-13 and F-19 NMR. The stereochemical assignment was based on intramolecular NOEs in conjunction with molecular modelling and semi-empirical methods, and confirmed by interligand NOEs in nitrogen chelate complexes derived from the title compounds. The nitrogen chelating ligands are involved in a rotation with respect to the ligand-palladium axis.

引用

页码：954 / 959

页数：6

共 24 条

[1] 2D NOESY OF PALLADIUM PI-ALLYL COMPLEXES - REPORTER LIGANDS, COMPLEX DYNAMICS, AND THE X-RAY STRUCTURE OF [PD(ETA-3-C4H7)(BPY)](CF3SO3) (BPY = BIPYRIDINE)
ALBINATI, A
KUNZ, RW
AMMANN, CJ
PREGOSIN, PS
[J]. ORGANOMETALLICS, 1991, 10 (06) : 1800 - 1806
[2] 2-DIMENSIONAL H-1 NOESY OF PD(II) PI-ALLYL COMPLEXES - THE CONCEPT OF REPORTER LIGANDS AND THE MOLECULAR-STRUCTURE OF [PD(ETA-3-CH2CCHCH2CH2CH2)(BIQUINOLINE)]CF3SO3
ALBINATI, A
AMMANN, C
PREGOSIN, PS
RUEGGER, H
[J]. ORGANOMETALLICS, 1990, 9 (06) : 1826 - 1833
[3] CHEMISTRY OF PDII COMPLEXES CONTAINING BOTH BINAP (2'2'-BIS(DIPHENYLPHOSPHINO)BINAPHTHYL) AND A ETA-3-PINENE OR ETA-3-ALLYL LIGAND - NMR-STUDIES ON [PD(ETA-3-C10H15)(S(-)BINAP)] (CF3SO3) - THE CRYSTAL-STRUCTURE OF [PD(ETA-3-C10H15)(4,4'-DIMETHYLBIPYRIDINE)](CF3SO3)
AMMANN, CJ
PREGOSIN, PS
RUEGGER, H
ALBINATI, A
LIANZA, F
KUNZ, RW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 423 (03) : 415 - 430
[4] ACETATO-BRIDGED ACETOXY- AND METHOXY-PALLADIUM ADDUCTS OF 1,5-CYCLOOCTADIENE
ANDERSON, CB
BURRESON, BJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1967, 7 (01) : 181 - &
[5] NUCLEAR MAGNETIC RESONANCE STUDIES OF RATE PROCESSES AND CONFORMATIONS .V. SYNCHRONOUS INVERSION AT 2 NITROGENS
ANDERSON, JE
LEHN, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (01) : 81 - &
[6] PALLADIUM-CATALYZED INTRAMOLECULAR 1,4-ADDITIONS TO CONJUGATED DIENES
BACKVALL, JE
[J]. PURE AND APPLIED CHEMISTRY, 1992, 64 (03) : 429 - 437
[7] STRUCTURE DETERMINATION AND SPECTRAL ASSIGNMENT BY PULSED POLARIZATION TRANSFER VIA LONG-RANGE H-1-C-13 COUPLINGS
BAX, A
[J]. JOURNAL OF MAGNETIC RESONANCE, 1984, 57 (02) : 314 - 318
[8] STRUCTURE DETERMINATION OF A TETRASACCHARIDE - TRANSIENT NUCLEAR OVERHAUSER EFFECTS IN THE ROTATING FRAME
BOTHNERBY, AA
STEPHENS, RL
LEE, JM
WARREN, CD
JEANLOZ, RW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) : 811 - 813
[9] REACTION OF METAL-ION COMPLEXES WITH HYDROCARBONS .4. FORMATION OF COMPLEXES OF TYPES DI-MU-ACETATO-BIS[(ETA-3ALLYL)PALLADIUM] AND TETRA-MU-ACETATO-DI(ETA-3ALLYL)TRIPALLADIUM BY REACTION OF MONO-OLEFINS AND 1,3-DIENES WITH PALLADIUM ACETATE
BROWN, RG
CHAUDHARI, RV
DAVIDSON, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (02): : 176 - 183
[10] REACTIONS OF BIS(CYCLO-OCTA-1,5-DIENE)PLATINUM WITH QUINONES - CRYSTAL-STRUCTURE OF [PT(ETA-4-C6H2O2(BUT2-2,6))(ETA-4-C8H12)]
CHETCUTI, MJ
HOWARD, JAK
PFEFFER, M
SPENCER, JL
STONE, FGA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (01): : 276 - 283

← 1 2 3 →