INTRAMOLECULAR HOST-GUEST COMPLEXES OF D-MONO-6-PHENYLALANYL-AMINO-6-DEOXY AND L-MONO-6-PHENYLALANYL-AMINO-6-DEOXY CYCLOMALTO-HEPTAOSES

被引:37
作者
PARROTLOPEZ, H
GALONS, H
COLEMAN, AW
DJEDAINI, F
KELLER, N
PERLY, B
机构
[1] UNIV PARIS 11,CNRS,UA 496,F-92296 CHATENAY MALABRY,FRANCE
[2] CENS,SERV CHIM MOLEC,F-91191 GIF SUR YVETTE,FRANCE
关键词
D O I
10.1016/0957-4166(90)90035-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Coupling of L- and D-phenylalanine to mono 6-amino-β-cyclodextrin leads to the formation of diastereoisomeric intramolecular inclusion compounds. The proton NMR spectra of the two products show clear chiral discrimination between the two molecules with regard to the interaction of the aromatic moieties with the cyclodextrin cavity. © 1990.
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页码:367 / 370
页数:4
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