PLATINUM DICHLORIDE COMPLEXES WITH (R,R)-[(BICYCLO[2.2.2]OCTANE-2,3-DIYL)BIS(METHYLENE)]BIS[DIPHENYLPHOSPHINE] OR BIS[5H-BENZO[B]PHOSPHININDOLE] - NEW CATALYST PRECURSORS FOR ENANTIOSELECTIVE HYDROFORMYLATION

被引：49

作者：

CONSIGLIO, G

NEFKENS, SCA

机构：

[1] Swiss Federal Institute of Technology, Department of Industrial and Engineering Chemistry, ETH-Zentrum

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86342-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of the platinum dichloride complexes with (R,R)-[(bicyclo [2.2.2]octane-2,3-diyl)bis(methylene)]bis[diphenylphosphine]- or bis[5H-benzo[b]-phosphinindole] is reported. The complexes have been tested as catalyst precursors for enantioselective hydroformylation of some aromatic olefins. Asymmetric inductions up to 85% have been obtained. © 1990.

引用

页码：417 / 420

页数：4

共 23 条

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