PLATINUM DICHLORIDE COMPLEXES WITH (R,R)-[(BICYCLO[2.2.2]OCTANE-2,3-DIYL)BIS(METHYLENE)]BIS[DIPHENYLPHOSPHINE] OR BIS[5H-BENZO[B]PHOSPHININDOLE] - NEW CATALYST PRECURSORS FOR ENANTIOSELECTIVE HYDROFORMYLATION

被引：49

作者：

CONSIGLIO, G

NEFKENS, SCA

机构：

[1] Swiss Federal Institute of Technology, Department of Industrial and Engineering Chemistry, ETH-Zentrum

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86342-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of the platinum dichloride complexes with (R,R)-[(bicyclo [2.2.2]octane-2,3-diyl)bis(methylene)]bis[diphenylphosphine]- or bis[5H-benzo[b]-phosphinindole] is reported. The complexes have been tested as catalyst precursors for enantioselective hydroformylation of some aromatic olefins. Asymmetric inductions up to 85% have been obtained. © 1990.

引用

页码：417 / 420

页数：4

共 23 条

[11] ASYMMETRIC HYDROFORMYLATION OF UNSATURATED ESTERS WITH PTCL(SNCL3)[(R,R)-DIOP] CATALYST
KOLLAR, L
CONSIGLIO, G
PINO, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 330 (1-2) : 305 - 314
[12] ASYMMETRIC HYDROFORMYLATION WITH PT-PHOSPHINE-SNCL2 AND PT-BISPHOSPHINE-CUCL2 (OR CUCL) CATALYTIC-SYSTEMS
KOLLAR, L
BAKOS, J
TOTH, I
HEIL, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) : 257 - 261
[13] MROWCA JJ, 1975, Patent No. 825835
[14] MROWCA JJ, 1975, Patent No. 3876672
[15] SYNTHESIS OF 2-ARYLPROPIONALDEHYDES THROUGH HYDROFORMYLATION
NEIBECKER, D
REAU, R
LECOLIER, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (22) : 5208 - 5210
[16] OJIMA I, 1985, ASYMMETRIC SYNTHESIS, V5, P103
[17] ASYMMETRIC HYDROFORMYLATION CATALYZED BY HOMOGENEOUS AND POLYMER-SUPPORTED PLATINUM COMPLEXES CONTAINING CHIRAL PHOSPHINE-LIGANDS
PARRINELLO, G
STILLE, JK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) : 7122 - 7127
[18] RAFFAELLI A, 1988, SYNTHESIS-STUTTGART, P893
[19] ROUNDHILL DM, 1987, COMPREHENSIVE COORDI, V5, P450
[20] DIPHOSPHINE COMPLEXES OF IRIDIUM(I), PALLADIUM(II), AND PLATINUM(II)
SANGER, AR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (20): : 1971 - 1976

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