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PHOSPHORIC-ACID DIESTERS PROTONATED POLYANILINE - PREPARATION, SPECTROSCOPIC PROPERTIES, AND PROCESSABILITY

被引：62
作者：
LASKA, J
PRON, A
LEFRANT, S
机构：
[1] TECH UNIV WARSAW, DEPT CHEM, PL-00664 WARSAW, POLAND
[2] UNIV NANTES, INST MAT, CNRS, UNITE MIXTE RECH 10, F-44072 NANTES, FRANCE
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1995年 / 33卷 / 09期
关键词：
POLYANILINE; PROCESSABILITY; PROTONATION;
D O I：
10.1002/pola.1995.080330904
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Aliphatic and aromatic diesters of phosphoric acid were tested as dopants improving processability of polyaniline (PANI) in its doped (conducting) state. It has been found that both aromatic and aliphatic diesters effectively protonate polyaniline, inducing at the same time its solubility. The protonated state has been confirmed by three independent spectroscopic methods (FTIR, Raman, and UV-vis-NIR). Both aromatic and aliphatic diesters of phosphoric acid plasticize polyaniline which, in turn, allows for the preparation of highly conducting films of PANI or highly conducting blends of PANI with classical nonconducting polymers by thermal processing. (C) 1995 John Wiley & Sons, Inc.
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页码：1437 / 1445
页数：9
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