SYNTHESIS BASED ON CYCLOHEXADIENES .4. NOVEL SYNTHESIS OF THE 6-ARYL-2,4-DIMETHOXYBENZOATES - ALTERNARIOL AND METHYL TRIMETHYLALTENUSIN

被引：23

作者：

KANAKAM, CC ^{[1
]}

MANI, NS ^{[1
]}

RAO, GSRS ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 08期

关键词：

D O I：

10.1039/p19900002233

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel method for the preparation of 6-aryl-2,4-dimethoxybenzoic acids involving the Alder-Rickert reaction of 1,5-dimethoxycyclohexa-1,4-dienes and arylpropiolic esters is described. This strategy has been extended to the synthesis of the mould metabolite alternariol and methyl trimethylaltenusin.

引用

页码：2233 / 2237

页数：5

共 17 条

[1] DIPHENYLENES .2. SYNTHESES OF SUBSTITUTED DIPHENYLENES AND OF RELATED DIPHENYLS [J].

BAKER, W ;

BARTON, JW ;

MCOMIE, JFW .

JOURNAL OF THE CHEMICAL SOCIETY, 1958, (AUG) :2658-2665

[2] STRATEGIES OF SYNTHESIS BASED ON CYCLOHEXADIENES .3. A NOVEL ROUTE TO MACROLIDE AROMATIC POLYKETIDES [J].

BIRCH, AJ ;

MANI, NS ;

RAO, GSRS .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (05) :1423-1427

[3]

BIRCH AJ, 1947, J CHEM SOC, P593

[4]

CADBY PA, 1973, AUST J CHEM, V26, P565

[5] METABOLITES OF SOME ALTERNARIA SPECIES - STRUCTURES OF ALTENUSIN AND DEHYDROALTENUSIN [J].

COOMBE, RG ;

JACOBS, JJ ;

WATSON, TR .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (11) :2343-&

[6] AUCUPARIN AND METHOXYAUCUPARIN, 2 PHENOLIC BIPHENYL DERIVATIVES FROM HEARTWOOD OF SORBUS AUCUPARIA (L.) [J].

ERDTMAN, H ;

FORSEN, S ;

ERIKSSON, G ;

NORIN, T .

ACTA CHEMICA SCANDINAVICA, 1963, 17 (04) :1151-&

[7]

FREEMAN CG, 1966, PHYTOCHEMISTRY, V5, P719

[8] GIBBERELLIC ACID .12. THE STEREOCHEMISTRY OF ALLOGIBBERIC ACID [J].

GROVE, JF ;

MULHOLLAND, TPC .

JOURNAL OF THE CHEMICAL SOCIETY, 1960, (JUL) :3007-3022

[9] FORMATION OF TRIANIONS OF 2,4,6-TRIKETONES - SYNTHESIS OF 3,5,7-TRIKETO ACIDS USING LITHIUM DIISOPROPYLAMIDE [J].

HARRIS, TM ;

MURPHY, GP ;

POJE, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (24) :7733-7741

[10] SYNTHESES BASED ON CYCLOHEXADIENES .2. CONVENIENT SYNTHESIS OF 6-ALKYLSALICYLATES, 6-ALKYL-2,4-DIHYDROXYBENZOATE, AND 2,5-DIALKYLRESORCINOLS [J].

KANAKAM, CC ;

MANI, NS ;

RAMANATHAN, H ;

RAO, GSRS .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (11) :1907-1913

← 1 2 →