ELECTRONIC-STRUCTURE OF THE ONE-ELECTRON OXIDATION-PRODUCT OF TRIPLE-DECKER LUTETIUM PHTHALOCYANINE TRIMER

被引：18

作者：

ISHIKAWA, N ^{[1
]}

KAIZU, Y ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM,MEGURO KU,TOKYO 152,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 236卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(95)00204-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The measurement of the electronic and ESR spectrum of triple-decker phthalocyanine trimer radical in solution is reported. The one-electron oxidation product of the soluble trimer ([(Pc)Lu(CRPc)Lu(Pc)]: Pc = phthalocyanine; CRPc = 15-crown-5 substituted Pc) in dichloromethane shows an ESR signal at g = 2.002(2) at 77 K, and an intense near-IR band at almost-equal-to 5 x 10(3) cm-1. The origin of the near-IR band (which corresponds to the near-IR band of the dimer radical [Lu(Pc)2] at almost-equal-to 7 x 10(3) cm-1) as well as bands in the Q-band region are discussed in terms of a localized orbital model.

引用

页码：50 / 56

页数：7

共 25 条

[11]

Peterson, Schramm, Stojakovic, Hoffman, Marks, A new class of highly conductive molecular solids: the partially oxidized phthalocyanines, Journal of the American Chemical Society, 99, (1977)

[12]

Martinsen, Palmer, Tanaka, Greene, Hoffman, Phys. Rev. B, 30, (1984)

[13]

Schramm, Scaringe, Stojakovic, Hoffman, Ibers, Marks, J. Am. Chem. Soc., 102, (1980)

[14]

Yakushi, Yamakado, Yoshitake, Kosugi, Kuroda, Kawamoto, Tanaka, Sugano, Kinoshita, Hino, Preparation and characterization of the cation radical salts of phthalocyanine and tetrabenzoporphyrin, Synthetic Metals, 29, (1989)

[15]

Hino, Matsumoto, Yamakado, Yakushi, Kuroda, Synth. Metals, 32, (1989)

[16]

Ishikawa, Kaizu, Chem. Phys. Letters, 228, (1994)

[17]

Koray, Ahsen, Bekaroglu, Preparation of a novel, soluble copper phthalocyanine with crown ether moieties, Journal of the Chemical Society, Chemical Communications, (1986)

[18]

Kobayashi, Nishiyama, A copper phthalocyanine with four crown ether voids, Journal of the Chemical Society, Chemical Communications, (1986)

[19]

Hendriks, Sielcken, Drenth, Nolte, Polytopic ligand systems: synthesis and complexation properties of a ?crowned? phthalocyanine, Journal of the Chemical Society, Chemical Communications, (1986)

[20]

Ishikawa, Ohno, Kaizu, Kobayashi, J. Phys. Chem., 96, (1992)

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