FROM MOLECULES TO ELECTROLYTES - ELECTROCHEMICAL AND THERMODYNAMIC ASPECTS OF THE INTERACTION OF PHENOL AND RESORCINOL BASED CALIXARENES WITH AMINES

被引：15

作者：

DENAMOR, AFD ^{[1
]}

BLACKETT, PM ^{[1
]}

PARDO, MTG ^{[1
]}

TANAKA, DAP ^{[1
]}

VELARDE, FJS ^{[1
]}

CABALEIRO, MC ^{[1
]}

机构：

[1] UNIV NACL SUR,INST QUIM ORGAN,RA-8000 BAHIA BLANCA,ARGENTINA

来源：

PURE AND APPLIED CHEMISTRY | 1993年 / 65卷 / 03期

关键词：

D O I：

10.1351/pac199365030415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An important consequence of the interaction of calix(n)arenes and amines is the generation of new electrolytes resulting from proton transfer reactions from the calix(n)arene molecule to the amine. A brief account on the contributions made in this area is presented. This is followed by recent electrochemical (conductimetric and potentiometric) and thermodynamic studies on the interaction of a phenol-based-calixarene and amines in non-aqueous media. The thermodynamics of extraction of amines by p-tert butyl calix(8)arene in the water-benzonitrile solvent system is discussed taking into account the parameters which contribute to the overall process. The results obtained from conductimetric and spectrophotometric studies on the interaction of a resorcinol-based calixarene and amines are presented.

引用

页码：415 / 422

页数：8