SYNTHETIC APPLICATIONS OF BIS(IMINOPHOSPHORANES) - ONE-POT PREPARATION OF RIGID BICYCLIC GUANIDINES

被引：48

作者：

MOLINA, P

ALAJARIN, M

VIDAL, A

机构：

[1] Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia, E-30071, Murcia, Campus de Espinardo

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 07期

关键词：

D O I：

10.1021/jo00059a015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one-pot synthesis of [6 + 6], [6 + 7], and [6 + 8] bicyclic guanidines based on a new method of dihydropyrimido annelation, which involves reaction of bis(iminophosphoranes) with aryl isocyanates or isothiocyanates is described. The method is also applicable for the preparation of chiral bicyclic guanidines.

引用

页码：1687 / 1695

页数：9

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