SYNTHESIS OF BETA,GAMMA-UNSATURATED D-ALPHA-AMINO ACIDS FROM L-CYSTEINE

被引：27

作者：

DUTHALER, RO

机构：

[1] Central Research Laboratories, Ciba-Geigy Ag, Basel, CH-4002, Post Office Box

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 06期

关键词：

D O I：

10.1002/anie.199107051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

D-alpha-Amino-acids 2 are accessible in high optical purity by acid hydrolysis of the 5-thiazolidinone 1. Compounds of the type 1 can be prepared in a few reaction steps from L-cysteine; during the conversion of 1 into 2 unsaturated residues R remain intact. Boc = tert-butoxycarbonyl.

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页码：705 / 707

页数：3

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