6-COORDINATED AND 7-COORDINATED MANGANESE(II) COMPLEXES OF QUATERPYRIDINE - SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND CATALYST FOR ALKENE EPOXIDATION

被引：30

作者：

CHAN, CW

CHE, CM

PENG, SM

机构：

[1] UNIV HONG KONG,DEPT CHEM,POKFULAM RD,HONG KONG,HONG KONG

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI,TAIWAN

来源：

POLYHEDRON | 1993年 / 12卷 / 18期

关键词：

D O I：

10.1016/S0277-5387(00)88253-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Mn(ClO4)2 . xH2O and Mn(CH3CO2)3 . xH2O with 2,2': 6',2'': 6'',2'''-quaterpyridine (QP) in acetonitrile or methanol gave the complexes [Mn(QP)(H2O)2] (ClO4)2 and [Mn(QP)(CH3CO2)(H2O)](ClO4), respectively. X-ray crystal structure determination revealed that the manganese atom is six-coordinated in the former, but seven-coordinated in the latter. Both complexes catalysed oxidation of alkenes by PhIO.

引用

页码：2169 / 2173

页数：5

共 11 条

[1] ANSELL CWG, 1983, POLYHEDRON, V2, P489
[2] SPECTROSCOPY, PHOTOPHYSICAL PROPERTIES, AND X-RAY CRYSTAL-STRUCTURE OF PLATINUM(II) COMPLEXES OF QUATERPYRIDINE
CHAN, CW
CHE, CM
CHENG, MC
WANG, Y
[J]. INORGANIC CHEMISTRY, 1992, 31 (23) : 4874 - 4878
[3] SYNTHESIS AND MOLECULAR-STRUCTURES OF NOVEL 7-COORDINATED OXO-RHENIUM(V) AND NITRIDO-RHENIUM(V) COMPLEXES OF 2,2'/6',2''/6'',2'''-QUATERPYRIDINE
CHE, CM
WANG, YP
YEUNG, KS
WONG, KY
PENG, SM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (18): : 2675 - 2677
[4] EFFECTS OF ELECTRODE SURFACE PRETREATMENTS ON THE ELECTROCHEMISTRY OF A MACROCYCLIC DIOXORUTHENIUM(VI) COMPLEX
CHE, CM
WONG, KY
ANSON, FC
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 226 (1-2) : 211 - 226
[5] CONSTABLE EC, 1982, POLYHEDRON, V1, P311, DOI 10.1016/S0277-5387(00)87171-5
[6] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES
CONSTABLE, EC
[J]. ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 : 69 - 121
[7] HOMOLEPTIC COMPLEXES OF 2,2'-BIPYRIDINE
CONSTABLE, EC
[J]. ADVANCES IN INORGANIC CHEMISTRY, 1989, 34 : 1 - 63
[8] THE PREPARATION AND STRUCTURAL CHARACTERIZATION OF A CHROMIUM(III) COMPLEX WITH A POTENTIALLY HELICATING LIGAND - THE X-RAY CRYSTAL-STRUCTURE OF TRANS-DICHLORO(2,2'6',2''6'',2'''-QUATERPYRIDINE-N,N',N'',N''')CHROMIUM(III) CHLORIDE TETRAHYDRATE
CONSTABLE, EC
ELDER, SM
TOCHER, DA
[J]. POLYHEDRON, 1992, 11 (11) : 1337 - 1342
[9] A CONVENIENT PREPARATION OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE AND BIS(ACETONITRILE)-(2,2'-6',2''-6'',2'''-QUATERPYRIDINE)NICKEL(II) HEXAFLUOROPHOSPHATE ACETONITRILE(1/1)
CONSTABLE, EC
ELDER, SM
HEALY, J
TOCHER, DA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (05): : 1669 - 1674
[10] INVESTIGATION INTO AROYLHYDRAZONES AS CHELATING-AGENTS .3. SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF COMPLEXES OF MN-II, CO-II, NI-II, CU-II, AND ZN-II WITH 2,6-DIACETYLPYRIDINE BIS(BENZOYLHYDRAZONE) AND X-RAY STRUCTURE OF AQUACHLORO[2,6-DIACETYLPYRIDINE "BIS(BENZOYLHYDRAZONE)]MANGANESE(II) CHLORIDE
LORENZINI, C
PELIZZI, C
PELIZZI, G
PREDIERI, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (04): : 721 - 727

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