STEREOCONTROLLED RADICAL REACTIONS IN CARBOHYDRATE AND NUCLEOSIDE CHEMISTRY

被引：31

作者：

BARTON, DHR

GERO, SD

QUICLETSIRE, B

SAMADI, M

机构：

[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE

[2] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(00)86288-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The radicals, generated by photolysis of 2,3-dimethyl ketals of N-hydroxy-2- thiopyridone uronic esters, reacted stereoselectively with electron deficient olefins leading to highly functionalised chain-elongated pentafuranosides, hexapyranosides and pentafuranosyl-nucleosides through the 4,5 and 4' radicals, respectively.

引用

页码：2123 / 2136

页数：14

共 26 条

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