PRIMARY AND SECONDARY OXYGEN-INDUCED C1S BINDING-ENERGY SHIFTS IN X-RAY PHOTOELECTRON-SPECTROSCOPY OF POLYMERS

被引：337

作者：

BRIGGS, D

BEAMSON, G

机构：

[1] ICI Plc, Wilton Materials Research Centre, Middlesbrough, Cleveland

来源：

ANALYTICAL CHEMISTRY | 1992年 / 64卷 / 15期

关键词：

D O I：

10.1021/ac00039a018

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A total of 43 polymers containing only C, H, and O have been studied using an X-ray photoelectron spectroscopy instrument capable of the highest energy resolution available to date. The primary aim was to reinvestigate the C1s binding energy shifts for oxygen functionalities and to systematically investigate secondary (beta) shifts for the first time. In addition, this large data set has revealed the effects of vibrational fine structure on C1s component line width/shape and the effects of shake-up/shake-off (in photoemission from C=O groups) on nonstoichiometry of C1s component intensities.

引用

页码：1729 / 1736

页数：8

共 26 条

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