SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .48. ORTHO-LITHIATION DIRECTED BY AMINO-GROUPS ON SILICON IN PHENYLSILANE DERIVATIVES

被引：20

作者：

TAMAO, K

YAO, H

TSUTSUMI, Y

ABE, H

HAYASHI, T

ITO, Y

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 20期

关键词：

D O I：

10.1016/0040-4039(90)80186-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phenylsilanes, which contain trimethylethylenediamino (Me2NCH2CH2NMe-) group(s) on silicon, undergo selective ortho lithiation by treatment with t-BuLi, providing a new method for the synthesis of ortho substituted phenylsilane derivatives. © 1990.

引用

页码：2925 / 2928

页数：4